Before I throw away the cartridge, do they not recycle them?

I always take mine to office supply stores or local events for recycling, haven't had any rejected yet.

What is the shelf life for these cartridges?

We suggest that the toner should be used within 18 months

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2PK Compatible TN-660 Toner Cartridge Replacement for Brother TN660 TN630 Toner for Brother HL-L2300D HL-L2320D HL-L2340DW HL L2360DW L2380DW MFC-L2700DW MFC-L2740DW DCP L2520DW L2540DW Printer

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